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Clausius–Clapeyron constant : ウィキペディア英語版 | Clausius–Clapeyron relation
The Clausius–Clapeyron relation, named after Rudolf Clausius and Benoît Paul Émile Clapeyron, is a way of characterizing a discontinuous phase transition between two phases of matter of a single constituent. On a pressure–temperature (P–T) diagram, the line separating the two phases is known as the coexistence curve. The Clausius–Clapeyron relation gives the slope of the tangents to this curve. Mathematically, : where is the slope of the tangent to the coexistence curve at any point, is the specific latent heat, is the temperature, is the specific volume change of the phase transition and is the specific entropy change of the phase transition. == Derivations ==
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